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Synthesis of ligand 4,4’-(1h,1’h-5,5’-bibenzo[d]imidazol-2,2’-diyl) dibenzoic acid: a new linker for MOFs

Thien Thanh Co 1, *
Toan Mai 1
Hong Thi Thu Nguyen 1
Quynh Ngoc Nguyen 1
Vu Pham Anh Ho 1
  1. University of Science, VNU-HCM
Correspondence to: Thien Thanh Co, University of Science, VNU-HCM. Email: pvphuc@vnuhcm.edu.vn.
Volume & Issue: Vol. 16 No. 2 (2013) | Page No.: 61-69 | DOI: 10.32508/stdj.v16i2.1453
Published: 2013-06-30

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Copyright The Author(s) 2023. This article is published with open access by Vietnam National University, Ho Chi Minh city, Vietnam. This article is distributed under the terms of the Creative Commons Attribution License (CC-BY 4.0) which permits any use, distribution, and reproduction in any medium, provided the original author(s) and the source are credited. 

Abstract

A novel ligand 4,4’-(1H,1’H-5,5’-bibenzo[D]imidazol-2,2’-diyl)dibenzoic acid, was synthesized and fully characterized by various spectroscopic methods such FT-IR, 1H, 13C-NMR and DEPT analysis. MOFs material derived from this ligand and zinc nitrate has been synthesized by solvothermal method. The structure of the new MOFs was examined by powder XRD, thermogravimetric analysis (TGA) and the nitrogen physical uptake reveal the surface area based on Langmuir theory is up to 147 m2/g.

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