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EXPERIMENTAL AND THEORETICAL ANALYSIS OF A CRITICAL CHEMICAL REACTION: DECOMPOSITION OF HYDROGEN PEROXIDE (H2O2)

Mai Thanh Phong 1
Carolina de Barros Aires 2
Volume & Issue: Vol. 11 No. 8 (2008) | Page No.: 28-36 | DOI: 10.32508/stdj.v11i8.2671
Published: 2008-08-31

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Copyright The Author(s) 2023. This article is published with open access by Vietnam National University, Ho Chi Minh city, Vietnam. This article is distributed under the terms of the Creative Commons Attribution License (CC-BY 4.0) which permits any use, distribution, and reproduction in any medium, provided the original author(s) and the source are credited. 

Abstract

The decomposition of hydrogen peroxide was studied using a reaction calorimeter. The solution of Iron (III) Nitrate was used as a homogeneous catalyst. The reaction rate was quantified from the course of the heat flux due to reaction measured during the experiments. To this end, the reaction rate was modeled as: a) a first order reaction, and b) an “mth” order reaction. The studies showed that the obtained results based on the assumption of a first order reaction were not good as expected, while the model based on “mth” order kinetics provided much better results and the experimental data could be well described.

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