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Synergetic catalytic effect of molybdenium (Mo) and chromnium (Cr) ions on HZSM-5 support for isomerization of n-hexane by reaction without hydrogen

Cai Van Huynh 1, *
Nhung Dinh Tran 1
Quyen Huynh 1
  1. VNUHCM-University of Technology
Correspondence to: Cai Van Huynh, VNUHCM-University of Technology. Email: pvphuc@vnuhcm.edu.vn.
Volume & Issue: Vol. 19 No. 4 (2016) | Page No.: 83-94 | DOI: 10.32508/stdj.v19i4.707
Published: 2016-12-31

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Copyright The Author(s) 2023. This article is published with open access by Vietnam National University, Ho Chi Minh city, Vietnam. This article is distributed under the terms of the Creative Commons Attribution License (CC-BY 4.0) which permits any use, distribution, and reproduction in any medium, provided the original author(s) and the source are credited. 

Abstract

Synergetic catalytic effect of molybdenium (Mo) and chromnium (Cr) ions on HZSM-5 support have been carried out. The catalyst of MoCr/HZSM-5 have been tested for iszomerization of n-hexane based on non-hydrogen reaction. The results showed that the catalytic synthesis by impregnating Mo and Cr on HZSM-5 support with the suitable amount ( Mo:10 %; Cr:3 %) did not change the basis structure of HZSM-5. The catalytic effect of Mo, Cr have been showed by catalytic testing results, for that the isoparaffin selectivity of MoCr/HZSM-5 is 46.5 % higher than in the case of Mo/HZSM-5 (43.56 %). The synergystic catalytic activity was clearly expressed by the dehydrogenation and hydrogenation role of Cr enhancing the stability of isomerization effect of Mo on MoCr/HZSM-5 catalyst for n-hexane’s isomerization reaction. Research results could be considered as the scienctific basis results for catalytic research applied to gasoline high quality production from the condensate feed by non-hydrogen technology in Vietnam.

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