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Co-doping of Ni, Cu on CoMo/TiO2 catalyst and their effect on the hydrocracking reaction for the synthesis of BHD (bio-hydrofined-diesel) from animal fat and vegetable oil

Quyen Huynh 1, *
Viet Tan Tran 1
Nhung Dinh Tran 1
Cai Van Huynh 1
  1. VNUHCM-University of Science
Correspondence to: Quyen Huynh, VNUHCM-University of Science. Email: pvphuc@vnuhcm.edu.vn.
Volume & Issue: Vol. 18 No. 4 (2015) | Page No.: 117-127 | DOI: 10.32508/stdj.v18i4.915
Published: 2015-12-30

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Copyright The Author(s) 2023. This article is published with open access by Vietnam National University, Ho Chi Minh city, Vietnam. This article is distributed under the terms of the Creative Commons Attribution License (CC-BY 4.0) which permits any use, distribution, and reproduction in any medium, provided the original author(s) and the source are credited. 

Abstract

BHD (Bio hydrofined diesel) was synthesized from animal fat and vegetable oil by hydrodeoxygenation with CoMo/TiO2 catalyst. To improve the quality and the quantity of BHD, the synthesis co-doping of Ni, Cu on CoMo/TiO2 catalyst and catalytic performance were investiagated. The catalytic performance of various Ni, Cu- CoMo/TiO2 catalysts were studied for the hydrodeoxygention reaction at a range of temperature 300-350 oC. Compared with the hydrodeoxygention reaction with CoMo/TiO2 catalyst, the cetane number of BHD and the conversion reaction were higher when the co-doping catalyst was used. In addition, the quantity of BHD was increased 3-5 % vol when the hydrodeoxygenation reaction was done with co-doping Cu-CoMo/TiO2 catalyst.

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