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Preparation of high quality polycrystalline silicon thin films by aluminum induced crystallization

Tu Linh Phan 1, *
Duy Phong Pham 1
Bach Thang Phan 1
Cao Vinh Tran 1
  1. University of Science, VNU-HCM
Correspondence to: Tu Linh Phan, University of Science, VNU-HCM. Email: pvphuc@vnuhcm.edu.vn.
Volume & Issue: Vol. 16 No. 1 (2013) | Page No.: 57-63 | DOI: 10.32508/stdj.v16i1.1419
Published: 2013-03-31

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Copyright The Author(s) 2023. This article is published with open access by Vietnam National University, Ho Chi Minh city, Vietnam. This article is distributed under the terms of the Creative Commons Attribution License (CC-BY 4.0) which permits any use, distribution, and reproduction in any medium, provided the original author(s) and the source are credited. 

Abstract

In this paper, high-quality polycrystalline silicon (poly-Si) thin films on glass substrates are formed by Aluminum-induced crystallization (AIC). In AIC processes, bi-layer structures of amorphous silicon (a-Si) / Al are transformed into ones of (Al+ residual Si)/ poly-Si after simply annealing at 500°C in vacuum furnace. After Al chemical etchings, it isobserved that the obtained structures are poly-Si thinfilms on glasses with some amount of residual Si as“ islands”scattered on theirsurfaces. The number of these “Si islands” remarkedly reduced by choosing an appropriate thickness ratio of pre-annealled Al and Si layers that prepared by magnetron dc sputtering. In this study, at initial Al/a-Si thickness ratio of 110/230 nm, the high-quality poly-Si thin films are formed with very few“Si islands” on the surfaces after AIC processes. Theobtained smooth surfaces are not appearing “dendritic” in optical transmission microscopy (OTM ) images, have large grain size of tens of nanometers in SEM images and have average surface roughness of about 2.8 nm in AFM images. In addition, XRD Ө -2Ө measurements show a strong Si (111) peak at the 2Ө angle of 28.5°, presenting good crystalline phases. The films also reveal good p-type electrical conductivityin that their high carrier concentration and mobility in Hall effect measurements are 1018 cm-3 and 48 cm2/Vs, respectively.

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