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Synthesis and characteristics of La0.6Sr0.4Co0.2Fe0.8O3-δ perovskite cathode material by microwave assisted sol – gel method

Mai Thi Ngoc Tran 1, *
Ha Ky Phuong Huynh 2
Vien Minh Le 2
Thang Manh Ngo 2
  1. University of Food Industry, HUFI-HCM
  2. Ho Chi Minh City University of Technology, VNU HCM
Correspondence to: Mai Thi Ngoc Tran, University of Food Industry, HUFI-HCM. Email: pvphuc@vnuhcm.edu.vn.
Volume & Issue: Vol. 19 No. 3 (2016) | Page No.: 41-49 | DOI: 10.32508/stdj.v19i3.584
Published: 2016-09-30

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Copyright The Author(s) 2023. This article is published with open access by Vietnam National University, Ho Chi Minh city, Vietnam. This article is distributed under the terms of the Creative Commons Attribution License (CC-BY 4.0) which permits any use, distribution, and reproduction in any medium, provided the original author(s) and the source are credited. 

Abstract

In this study, LSCF 6428 was synthesized by microwave assisted sol – gel method. XRD and SEM analyses were used to determine the single-phase and nanocrystalline structure. Properties of this perovskite material including specific area, thermal expansion coefficient (TEC) and resistance of cathode were studied. The results showed that well-crystalline perovskite was obtained at microwaved of 500 W in 10 minutes, stirred at 90 oC in 2 hours and calcined at 900 oC in 1 hours. The surface area of the material was 13.384 m2/g. The properties of materials were also improved by mixing with Gadolinium doped ceria (GDC) at the ratio 7:3 (w/w). At this ratio, TEC of composite matched with electrolyte. The resistance of cathode was 0.17 – 0.2 Ω in the range of temperature from 580 – 700 oC. Microwave assisted sol – gel was an easy, economical and time – saving method to synthesis LSCF 6428 for Single Chamber - Solid oxide fuel cell (SC-SOFC) cathode application.

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